P. Andrew Evans Ordre des livres

The major emphasis here is on enantioselective reactions using asymmetric catalysts. Examples from the total synthesis of various natural and unnatural targets validates the utility of the synthetic methods. Specific topics discussed: cycloaddition, cycloisomerization and sigmatropic rearrangement reactions, allylic and carbonyl functionalization reactions, metal-catalyzed cross-coupling reactions, desymmetrization, fluorination, polymerization and sulfide oxidation reactions. This volume is part of a 3-volume set: Science of Synthesis Stereoselective Synthesis Workbench Edition Further information about Stereoselective Synthesis (including sample pages and the table of contents)

The major emphasis here is on enantioselective reactions using asymmetric catalysts. Examples from the total synthesis of various natural and unnatural targets validates the utility of the synthetic methods. Specific topics discussed: cycloaddition, cycloisomerization and sigmatropic rearrangement reactions, allylic and carbonyl functionalization reactions, metal-catalyzed cross-coupling reactions, desymmetrization, fluorination, polymerization and sulfide oxidation reactions. This volume is part of a 3-volume set: Science of Synthesis Stereoselective Synthesis Workbench EditionFurther information about Stereoselective Synthesis (including sample pages and the table of contents)

Rhodium is an invaluable metal known for its unique catalytic abilities in various synthetic transformations, including hydrogenation, C-H activation, and allylic substitution. The increasing number of articles on this topic highlights its significance. P. Andrew Evans has curated a comprehensive resource featuring contributions from leading experts in rhodium-catalyzed reactions. This book covers a wide range of developments, such as Rhodium-Catalyzed Asymmetric Hydrogenation, Hydroborations, and the Asymmetric Addition of Organometallic Reagents to Electron Deficient Olefins. It also discusses recent advances in Rhodium(I)-Catalyzed Asymmetric Olefin Isomerization, Hydroformylation, and Silylformylation reactions, along with carbon-carbon bond-forming reactions starting from Rh-H or Rh-Si species. Other topics include cycloisomerization, cyclotrimerization, and various carbocyclization reactions. The book also addresses chiral dirhodium(II) carboxamidates for asymmetric cyclopropanation, C-H insertion reactions, and oxidative amination. This essential reference text serves researchers at all levels in organic chemistry, providing an invaluable overview of significant developments and making it a vital resource for academics and professionals in pharmaceutical and agrochemical sectors.